Risk assessment of the utilization of basic oxygen furnace slag (BOFS) as soil liming material : Oxidation risk and the chemical bioavailability of chromium species

Peer reviewe

Effect of cumulative fertilizer dressings on the phosphorus status of mineral soils I Changes in inorganic phosphorus fractions

Surface soil samples were collected from 16 P fertilization trials before onset of the experiments and after seven years of cultivation. The changes in the inorganic P fractions were investigated in plots amended annually with 0, 30 or 60 kg of P ha-1. In the clay soils, cultivation without P fertilization depleted the NH4F-extractable and NaOH-extractable P reserves by 22—69 kg ha-1 ; in the coarser soils, the respective depletion was 8—140 kg ha-1. H2S04-soluble P decreased in seven soils by 16—34 kg ha-1. In the plots amended totally with 210 or 420 kg of P ha-1, on the other hand, these P fractions increased by 24—174 and 46—368 kg ha-1, respectively. The higher the P dressing was, the more the added P tended to accumulate in the fluoride-soluble form as compared to the alkali-soluble form

Relationship between phosphorus intensity and capacity parameters in Finnish mineral soils: I Interpretation and application of phosphorus sorption-desorption isotherms

The interpretation and application of two types of P isotherms were elucidated by means of sorption-desorption graphs of two surface soil samples. The isotherm expressing the retention or removal of P as a function of P application indicates the direction and extent of reactions at a given initial stage. The isotherm describing the sorption or desorption as a function of P concentration in the final solution after events illustrates the P buffering power of the soil. By using simultaneously the isotherms of both types, all information included can be integrated and the graphs can be used as a dynamic model describing P exchange

Sensitivity of soil phosphorus tests in predicting the potential risk of phosphorus loss from pasture soil

The objective of this study was to examine the effects of urine and dung additions on the phosphorus (P) chemistry of pasture land and to compare the sensitivity of two soil extraction methods in assessing the P-loading risk. In a field experiment, urine and dung were added to soil in amounts corresponding to single excrement portions and the soil samples, taken at certain intervals, were analysed for pHH2O, acid ammonium acetate extractable P (PAc) and water extractable total P (TPw), and molybdate reactive P (MRPw). Urine additions immediately increased soil pH and MRPw, but no such response was observed in PAc extraction due to the low pH (4.65) of the extractant enhancing the resorption of P. The PAc responded to the dunginduced increase in soil total P similarly as did Pw, which suggests that both tests can serve to detect areas of high P concentration. However, water extraction was a more sensitive method for estimating short-term changes in P solubility. In pasture soils, the risk of P loss increases as a result of the interaction of urination and high P concentration in the topsoil resulting from continuous dung excretion

Leaching of plant nutrients from cultivated soils: II Leaching of anions

Leaching of anions from three soil samples (sand, fine sand and sandy clay) representing the plough layer was studied in a lysimeter experiment under conditions corresponding to the fallow. The effect of fertilization and that of acid irrigation solution on the amounts of anions washed out was also studied. The extraction of anions from different soils seems to correspond to that of cations; the coarser the soil, the higher the nutrient losses. This was valid for nitrate and sulfate, but the amounts of phosphate extracted were insignificant. The sum of the anion equivalents leached was lower than the respective sum of cations in all the leachates indicating that a part of the cations was leached as bicarbonate. The physical properties of the soil regulating the infiltration of water affect the movement of anions bonded non-specifically. The anions in pores of soil aggregates seem to be protected against leaching to a certain degree. However, the biological value of an anion is an important factor. It seems that microbiological processes may decrease the leaching losses of nitrate

Soil response to acid input in a titration experiment

Cultivated surface soil samples of an acid Gleysol (soil 1, pH 4.9) and a slightly acid Podzol (soil 2, pH 6.7) were equilibrated for 48 h with oto 144 meq H+ kg-1 by a batch technique designed to simulate reactions of acid load with soil constituents. The pH of the titration suspensions ranged in soil 1 from 5.6 to 3.3, in soil 2 from 7.2 to 4.7. The exchange reaction with base cations on variable charge sites was an important mechanism for H+ inactivation. The quantities of cation equivalents released were, however, lower than the proton equivalents added. Calcium dominated the supernatant solutions, but as related to exchangeable reserves. Mg seemed to be more susceptible to acidification at high soil pH. Protons were also consumed in the mobilization of divalent base cations from a non-exchangeable pool to an exchangeable one. The experimental soils differed in their response of acid cation fractions to proton loading. In the rather neutral soil 2, the quantities of soluble and exchangeable acid cations were very low and not affected by acidification. The Al dissolved by proton attack was immobilized by complexation reactions. This mechanism did not operate in the acid soil 1 where the proton loading markedly increased the exchangeable Al pool and, consequently, the soluble Al in the supernatant solution. This was associated with a simultaneous reduction in the complexed Al and a small increase in complexed Fe. Furthermore, acidification diminished the effective cation exchange capacity (ECEC) decisively less in soil 1 than in soil 2, because the increase in exchangeable Al markedly compensated the reduction in the exchangeable base cations. As compared to freelydrained systems, the batch titration overestimated the release of Al to solution phase

Effect of decreasing acidity on the extractability of inorganic soil phosphorus

The extractability of P by the water and anion exchange resin methods and reactions of soil inorganic P were investigated with seven acid mineral soil samples incubated with KOH solutions of various concentrations. The results were compared with the analytical data obtained from three soil samples incubated in a prolonged liming experiment. The resin extraction method proved more effective than the water extraction method. The amounts of P desorbed by both methods seemed to increase exponentially as the pH in the soil suspensions rose. The factors involved were discussed. On the basis of fractionation analyses P reacting to changes in the pH and participating in desorption processes was supposed to originate from secondary NH4F and NaOH soluble reserves. In general, as the acidity decreased NH4F-P increased at the expense of NaOH-P. In heavily limed gyttja soil also H2SO4-P increased. This was possibly induced by the precipitation of mobilized P as a Ca compound. The significance of pH in the extractability of soil P seemed somewhat to lessen as the amount of secondary P increased. The results were in accordance with the conception that liming improves the availability of inorganic P to plants and reduces the need for P fertilization. However, increasing of the soil pH involves the risk that P is more easily desorbed to the recipient water by the eroded soil material carried into the watercourse. Therefore, intensive liming is not recommendable close to the shoreline. Further, it should be taken into account that liming of lakes may also result in eutrophication as desorption of sedimentary inorganic P is enhanced

Anionic nanofibrillated cellulose - a sustainable agent to recover highly soluble salts from industrial wastewaters

Utilisation of sodium (Na+) containing alkali in the neutralisation of acidic industrial process waters rich in sulphate (SO4 2−) produces effluents high in sodium sulphate (Na2SO4) reluctant to precipitate. Discharge of the saline effluents leads to permanent chemical stratification of the recipient freshwater systems, which prevents their annual overturn and the subsequent oxygen supply to hypolimnion. Novel and sustainable technologies are desperately needed to prevent the hazardous environmental impacts of saline effluents. We investigated the ability of anionic nanofibrillated cellulose (NFC) gels of three different consistencies to recover solubilised Na+ and SO4 2− from authentic circumneutral mining water onto a solid phase. The water was treated with the NFC gels in three sequential batches at three sorbent-to-solution ratios. NFC-induced changes in the ion concentrations were determined to calculate the Na+ and SO4 2− retention capacity and purification efficiency of the NFC gels. All NFC gels efficiently and coincidentally removed Na+ and SO4 2− from the mining water. We concluded that Na+ ions electrostatically adsorbed onto the deprotonated carboxyl groups of the anionic NFC and attracted SO4 2− ions which also acted as bridging anions between the neighbouring nanofibrils. Decrease in the consistency of the NFC gel enhanced accessibility of the sorption sites and, consequently, promoted the ion retention. A high sorbent-to-solution ratio favoured the intermolecular interactions within the NFC gels, thus decreasing the number of available sorption sites. A high ionic strength of the effluent favoured the ion retention, indicating that anionic NFC is particularly suitable for the treatment of highly saline solutions. The best purification result was obtained at a moderate sorbent-to-solution ratio with a dilute NFC gel. This lowers the demand for the cellulose raw material and the treatment expenses. We conclude that anionic NFC, made of renewable materials, may serve as an efficient and sustainable purification agent for removal and recycling of highly soluble Na+ and SO4 2−from industrial effluentsPeer reviewe

Base-neutralizing capacity of Finnish mineral soils

The base-neutralizing capacity, BMC7 (OH- as meq kg-1 needed to raise soil pH to 7), was determined graphically from curves obtained in KOH titration (at a constant ionic strength of I = 0.1). In 84 soil samples, BMC7 amounted to 0—316 meq kg-1, being highest in the heavy clay soils and lowest in the non-clay soils. In different textural groups, BMC7 seemed most markedly to be dependent on the initial soil pH, followed by organic C or oxalate soluble Al, in the coarser clays also on clay content. The results evidence that in determination of lime requirement, attention should be paid to the capacity of soil acidity. In routine soil testing, detailed lime recommendations for various soil types are needed